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Low Blooming Flame Retardant Based on Phosphorus and Silicone System for PA/HTPA

FR-AHP01 is a white powdery non-halogenated flame retardant based on phosphorus and silicon system for polyamide (nylon/ PA) with low blooming.
  • FR-AHP01

  • YINYUAN New Materials

  • White Powder

  • < 0.2

  • 20-40

  • > 350

  • Glass Fibre Reinforced and Non-reinforced PA6/66, HTPA

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FR-AHP01

Low Blooming Flame Retardant Based on Phosphorus and Silicone System for PA/HTPA



Product Description

FR-AHP01 is a white powder, non-halogenated flame retardant based on phosphorus and silicon system for polyamide (nylon/ PA) and high temperature PA. This product achieves its flame retardant effect via a combined gas phase and condensed phase mode of action. FR-AHP01 is developed for high temperature PA, which has excellent compatibility with polymers. It has benefits on low addition amount, low blooming, and low mold corrosion during processing in contrast to commercial phosphorus-based or phosphorus-nitrogen-based products.


FR-AHP01 is particularly suitable for the used of nylon (glass-fibre reinforced and non-reinforced nylon6 or 66), with excellent mechanical and electrical properties, in terms of good insulation, good colour stability, and low blooming, showing a high-potential for PA applications.



Specifications:

Characteristics

Unit

Target Value

Appearance


White powder

Density

g/cm3

1.38-1.40

Moisture/ Water

% (w/w)

< 0.2

Decomposition Temperature

> 350

Average Particle Size (D50)

μm

20-40



Applications:

In the 30% glass fibre (GF) reinforced PA6 or PA66, a dosage of 13-14% (by wt.) of FR-AHP01 is usually sufficient to obtain UL94 V-0 rating (1.6 mm), with a notch impact strength higher than 12 kJ/m2 .


FR-AHP01 achieves its excellent flame retardant effect via a combined gas phase and condensed phase mode of action, as well as flame retarded nylon exhibits low blooming, fewer appearance defects (flow marks), and less mold deposit. It also meets most efficient flame retardant grade regarding high temperature and high humidity (85℃ and 85%RH) for 1000 hours, with negligible blooming. 


FR-AHP01 flame retarded nylon exhibits excellent electrical and physical properties, in terms of high CTI value above 600V, good colourability (particularly suitable for white, whiteness > 92), and low graying probability of injection molding for long term.


Formulation:

Characteristics

Unit

Formula A

Formula B

Nylon 6/ 30GF

%, (w/w)

85.0

-

Nylon 66/ 30GF

%, (w/w)

-

86.0

FR-AHP01

%, (w/w)

14.0

13.0

Pentaerythrityl Tetrastearate, PETS

%, (w/w)

0.5

0.5

Silicone Powder

%, (w/w)

0.5

0.5


Physical Property Data:

Characteristics

Test Method

Unit

Formula A

Formula B

Density

ASTM D792

g/ cm3

1.452

1.454

Melt Index

ASTM D1238

g/ 10min

25.6

23.6

Tensile Strength

ASTM D638

MPa

126

142

Elongation at Break

ASTM D638

%

1.8

2.2

Bending Strength

ASTM D790

MPa

208

225

Notch Impact Strength

ASTM D256

kJ/m2

14.3

14.2

Flame Retardant Grade

UL94


V-0 (1.6mm)

V-0 (1.6mm)



Packing and Handling:

Delivery form:

White powder


Packing:

FR-AHP01 is packed in paper-plastic bags with polyethylene inliner, 25kg per package.


Storage:

FR-AHP01 must be sealed, stored in a dry and cool place.



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